Entries by groupdimocat

The adaptive aromaticity of metallapentalenes in the Front Cover of Chem. Eur. J.!

The Chemistry: A European Journal features in its FRONT COVER of issue number 57 of volume 26 the recently published article “Proving the origin of adaptive aromaticity in 16-valence-electron metallapentalenes”. The work has been carried out by Prof. Jun Zhu at the University of Xiamen and Dandan Chen, Dr. Dariusz W. Szczepanik, and Prof. Miquel Solà members of […]

A Review on Mechanistic Studies of Transition-Metal Catalyzed [2+2+2] Cycloaddition Reactions

The development of catalytic methodologies involving the formation of C-C bonds to enable the generation of cyclic systems constitutes a field of great relevance in synthetic organic chemistry. One paradigmatic process to accomplish this goal efficiently is the transition-metal catalyzed [2+2+2] cycloaddition reaction since it permits the formation of a wide range of highly functionalized […]

The aromaticity of boron clusters in the Front Cover of JACS!

The Journal of the American Chemical Society (JACS) features in its FRONT COVER the recently published article “Too Persistent to Give Up: Aromaticity in Boron Clusters Survives Radical Structural Changes”. The work has been carried out by Prof. Francesc Teixidor, Prof. Clara Viñas, and Dr. Ines Bennour of the Institute of Materials Science of Barcelona (ICMAB-CSIC), Prof. Jordi Poater […]

Aromaticity in Boron Clusters Survives Radical Structural Changes

Whereas the aromaticity of closo boranes is widely accepted, less is known about the aromaticity of nido boranes. This work carried out by Prof. Francesc Teixidor, Prof. Clara Viñas, and Dr. Ines Bennour of the Institute of Materials Science of Barcelona (ICMAB-CSIC), Prof. Jordi Poater at the University of Barcelona (previous DiMoCat member) and Sílvia Escayola […]

Discovered a new non-covalent interaction between boron nido clusters and aromatic rings

Exploration and comprehension of chemical bonding is one of the central tasks in chemistry. Here, a new non‐covalent interaction, a nido‐cage···π bond, is discovered in a collaborative work between Deshuang Du and Prof. Yan from Nanjing University and Prof. Jordi Poater at the University of Barcelona (previous DiMoCat member) and Prof. Miquel Solà from the […]